22 May 2021, Circuit de Monaco, Round 5
| Position | Driver | Team | Q1 | Q2 | Q3 |
|---|---|---|---|---|---|
| 1 | Charles Leclerc | Scuderia Ferrari | 1:11.113 | 1:10.597 | 1:10.346 |
| 2 | Max Verstappen | Red Bull Racing | 1:11.124 | 1:10.650 | 1:10.576 |
| 3 | Valtteri Bottas | Mercedes Formula 1 Team | 1:10.938 | 1:10.695 | 1:10.601 |
| 4 | Carlos Sainz | Scuderia Ferrari | 1:11.324 | 1:10.806 | 1:10.611 |
| 5 | Lando Norris | McLaren Formula 1 Team | 1:11.321 | 1:11.031 | 1:10.620 |
| 6 | Pierre Gasly | AlphaTauri | 1:11.560 | 1:11.179 | 1:10.900 |
| 7 | Lewis Hamilton | Mercedes Formula 1 Team | 1:11.622 | 1:11.116 | 1:11.095 |
| 8 | Sebastian Vettel | Aston Martin F1 Team | 1:12.078 | 1:11.309 | 1:11.419 |
| 9 | Sergio Pérez | Red Bull Racing | 1:11.644 | 1:11.019 | 1:11.573 |
| 10 | Antonio Giovinazzi | Alfa Romeo | 1:11.658 | 1:11.409 | 1:11.779 |
| 11 | Esteban Ocon | Alpine F1 Team | 1:11.740 | 1:11.486 | |
| 12 | Daniel Ricciardo | McLaren Formula 1 Team | 1:11.747 | 1:11.598 | |
| 13 | Lance Stroll | Aston Martin F1 Team | 1:11.979 | 1:11.600 | |
| 14 | Kimi Räikkönen | Alfa Romeo | 1:11.899 | 1:11.642 | |
| 15 | George Russell | Williams Racing | 1:12.016 | 1:11.830 | |
| 16 | Yuki Tsunoda | AlphaTauri | 1:12.096 | ||
| 17 | Fernando Alonso | Alpine F1 Team | 1:12.205 | ||
| 18 | Nicholas Latifi | Williams Racing | 1:12.366 | ||
| 19 | Nikita Mazepin | Haas F1 Team | 1:12.958 |
