8 May 2021, Circuit de Barcelona-Catalunya, Round 4
| Position | Driver | Team | Q1 | Q2 | Q3 |
|---|---|---|---|---|---|
| 1 | Lewis Hamilton | Mercedes Formula 1 Team | 1:18.245 | 1:17.166 | 1:16.741 |
| 2 | Max Verstappen | Red Bull Racing | 1:18.090 | 1:16.922 | 1:16.777 |
| 3 | Valtteri Bottas | Mercedes Formula 1 Team | 1:18.005 | 1:17.142 | 1:16.873 |
| 4 | Charles Leclerc | Scuderia Ferrari | 1:18.041 | 1:17.717 | 1:17.510 |
| 5 | Esteban Ocon | Alpine F1 Team | 1:18.281 | 1:17.743 | 1:17.580 |
| 6 | Carlos Sainz | Scuderia Ferrari | 1:18.205 | 1:17.656 | 1:17.620 |
| 7 | Daniel Ricciardo | McLaren Formula 1 Team | 1:18.264 | 1:17.719 | 1:17.622 |
| 8 | Sergio Pérez | Red Bull Racing | 1:18.203 | 1:17.669 | 1:17.701 |
| 9 | Lando Norris | McLaren Formula 1 Team | 1:17.821 | 1:17.696 | 1:18.010 |
| 10 | Fernando Alonso | Alpine F1 Team | 1:18.281 | 1:17.966 | 1:18.147 |
| 11 | Lance Stroll | Aston Martin F1 Team | 1:18.241 | 1:17.974 | |
| 12 | Pierre Gasly | AlphaTauri | 1:18.190 | 1:17.982 | |
| 13 | Sebastian Vettel | Aston Martin F1 Team | 1:18.289 | 1:18.079 | |
| 14 | Antonio Giovinazzi | Alfa Romeo | 1:18.549 | 1:18.356 | |
| 15 | George Russell | Williams Racing | 1:18.445 | 1:19.154 | |
| 16 | Yuki Tsunoda | AlphaTauri | 1:18.556 | ||
| 17 | Kimi Räikkönen | Alfa Romeo | 1:18.917 | ||
| 18 | Mick Schumacher | Haas F1 Team | 1:19.117 | ||
| 19 | Nicholas Latifi | Williams Racing | 1:19.219 | ||
| 20 | Nikita Mazepin | Haas F1 Team | 1:19.807 |
