6 Nov 2021, Autódromo Hermanos Rodríguez, Round 18
| Position | Driver | Team | Q1 | Q2 | Q3 |
|---|---|---|---|---|---|
| 1 | Valtteri Bottas | Mercedes Formula 1 Team | 1:16.727 | 1:16.864 | 1:15.875 |
| 2 | Lewis Hamilton | Mercedes Formula 1 Team | 1:17.207 | 1:16.474 | 1:16.020 |
| 3 | Max Verstappen | Red Bull Racing | 1:16.788 | 1:16.483 | 1:16.225 |
| 4 | Sergio Pérez | Red Bull Racing | 1:17.003 | 1:17.055 | 1:16.342 |
| 5 | Pierre Gasly | AlphaTauri | 1:16.908 | 1:16.955 | 1:16.456 |
| 6 | Carlos Sainz | Scuderia Ferrari | 1:17.517 | 1:17.248 | 1:16.761 |
| 7 | Daniel Ricciardo | McLaren Formula 1 Team | 1:17.719 | 1:17.092 | 1:16.763 |
| 8 | Charles Leclerc | Scuderia Ferrari | 1:16.748 | 1:17.034 | 1:16.837 |
| 9 | Yuki Tsunoda | AlphaTauri | 1:17.330 | 1:16.701 | 1:17.158 |
| 10 | Lando Norris | McLaren Formula 1 Team | 1:17.569 | 1:17.473 | 1:36.830 |
| 11 | Sebastian Vettel | Aston Martin F1 Team | 1:17.502 | 1:17.746 | |
| 12 | Kimi Räikkönen | Alfa Romeo | 1:17.606 | 1:17.958 | |
| 13 | George Russell | Williams Racing | 1:17.958 | 1:18.172 | |
| 14 | Antonio Giovinazzi | Alfa Romeo | 1:17.897 | 1:18.290 | |
| 15 | Esteban Ocon | Alpine F1 Team | 1:18.126 | 1:18.405 | |
| 16 | Fernando Alonso | Alpine F1 Team | 1:18.452 | ||
| 17 | Nicholas Latifi | Williams Racing | 1:18.756 | ||
| 18 | Mick Schumacher | Haas F1 Team | 1:18.858 | ||
| 19 | Nikita Mazepin | Haas F1 Team | 1:19.303 | ||
| 20 | Lance Stroll | Aston Martin F1 Team | 1:20.873 |
